| 1. Round | 11/09/1966 | Real Zaragoza | - | Espanyol Barcelona | 2:0 | ||||
| 2. Round | 18/09/1966 | Espanyol Barcelona | - | Sevilla FC | 3:1 | ||||
| 3. Round | 25/09/1966 | Real Madrid | - | Espanyol Barcelona | 1:1 | ||||
| 4. Round | 02/10/1966 | Espanyol Barcelona | - | Hércules CF | 4:1 | ||||
| 8. Round | 06/11/1966 | Espanyol Barcelona | - | Valencia CF | 2:1 | ||||
| 9. Round | 13/11/1966 | Córdoba CF | - | Espanyol Barcelona | 2:0 | ||||
| 10. Round | 20/11/1966 | Espanyol Barcelona | - | Atlético Madrid | 1:0 | ||||
| 11. Round | 27/11/1966 | CE Sabadell | - | Espanyol Barcelona | 0:1 | ||||
| 29. Round | 16/04/1967 | Espanyol Barcelona | - | UD Las Palmas | 1:1 | ||||
| 30. Round | 23/04/1967 | Granada CF | - | Espanyol Barcelona | 0:3 |
Spain