| 1. Round | 11/09/1966 | Hércules CF | - | CE Sabadell | 0:0 | ||||
| 2. Round | 18/09/1966 | Elche CF | - | Hércules CF | 4:0 | ||||
| 7. Round | 30/10/1966 | Hércules CF | - | Sevilla FC | 2:1 | ||||
| 8. Round | 06/11/1966 | Real Madrid | - | Hércules CF | 2:1 | ||||
| 11. Round | 27/11/1966 | FC Barcelona | - | Hércules CF | 4:1 | ||||
| 13. Round | 11/12/1966 | Valencia CF | - | Hércules CF | 4:0 | ||||
| 14. Round | 18/12/1966 | Hércules CF | - | Córdoba CF | 1:1 | ||||
| 16. Round | 08/01/1967 | CE Sabadell | - | Hércules CF | 5:2 | ||||
| 17. Round | 15/01/1967 | Hércules CF | - | Elche CF | 1:3 |  |
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| 22. Round | 26/02/1967 | Sevilla FC | - | Hércules CF | 0:0 | ||||
| 23. Round | 05/03/1967 | Hércules CF | - | Real Madrid | 0:2 | ||||
| 24. Round | 12/03/1967 | UD Las Palmas | - | Hércules CF | 0:1 | ||||
| 25. Round | 19/03/1967 | Athletic Club | - | Hércules CF | 0:0 | ||||
| 26. Round | 26/03/1967 | Hércules CF | - | FC Barcelona | 1:1 | ||||
| 27. Round | 02/04/1967 | Deportivo La Coruña | - | Hércules CF | 1:0 | ||||
| 28. Round | 09/04/1967 | Hércules CF | - | Valencia CF | 4:1 | ||||
| 29. Round | 16/04/1967 | Córdoba CF | - | Hércules CF | 1:1 | ||||
| 30. Round | 23/04/1967 | Hércules CF | - | Atlético Madrid | 2:4 |
Spain