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| 1st(1st leg) | Atlético Mineiro | - | Athletico Paranaense | 1:0 (1:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Atlético Mineiro | 3:5 (2:0, 2:1, 2:1) pso | ||
| 1st(1st leg): 02/05/2000 | 2nd (2nd leg): 11/05/2000 | Winner: Atlético Mineiro | ||||
| 1st(1st leg) | CF América | - | América de Cali | 2:1 (1:1) | ||
| 2nd (2nd leg) | América de Cali | - | CF América | 2:3 (1:1) | ||
| 1st(1st leg): 02/05/2000 | 2nd (2nd leg): 09/05/2000 | Winner: CF América | ||||
| 1st(1st leg) | El Nacional | - | Boca Juniors | 0:0 (0:0) | ||
| 2nd (2nd leg) | Boca Juniors | - | El Nacional | 5:3 (5:1) | ||
| 1st(1st leg): 03/05/2000 | 2nd (2nd leg): 09/05/2000 | Winner: Boca Juniors | ||||
| 1st(1st leg) | Rosario Central | - | Corinthians SP | 3:2 (1:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Rosario Central | 4:3 (1:1, 3:2, 3:2) pso | ||
| 1st(1st leg): 03/05/2000 | 2nd (2nd leg): 09/05/2000 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Atlas Guadalajara | - | Atlético Junior | 2:0 (0:0) | ||
| 2nd (2nd leg) | Atlético Junior | - | Atlas Guadalajara | 1:3 (0:1) | ||
| 1st(1st leg): 03/05/2000 | 2nd (2nd leg): 10/05/2000 | Winner: Atlas Guadalajara | ||||
| 1st(1st leg) | Nacional | - | Bolívar | 3:0 (1:0) | ||
| 2nd (2nd leg) | Bolívar | - | Nacional | 5:3 (3:0, 3:0, 3:0) pso | ||
| 1st(1st leg): 03/05/2000 | 2nd (2nd leg): 10/05/2000 | Winner: Bolívar | ||||
| 1st(1st leg) | Cerro Porteño | - | River Plate | 0:4 (0:3) | ||
| 2nd (2nd leg) | River Plate | - | Cerro Porteño | 1:0 (0:0) | ||
| 1st(1st leg): 04/05/2000 | 2nd (2nd leg): 10/05/2000 | Winner: River Plate | ||||
| 1st(1st leg) | Peñarol | - | Palmeiras | 2:0 (1:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Peñarol | 3:2 (2:0, 3:1, 3:1) pso | ||
| 1st(1st leg): 04/05/2000 | 2nd (2nd leg): 11/05/2000 | Winner: Palmeiras | ||||
