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| 1st(1st leg) | Boca Juniors | - | Atlas Guadalajara | 2:2 (1:1) | ||
| 2nd (2nd leg) | Atlas Guadalajara | - | Boca Juniors | 0:3 (0:3) | ||
| 1st(1st leg): 14/05/2008 23:15 | 2nd (2nd leg): 21/05/2008 23:25 | Winner: Boca Juniors | ||||
| 1st(1st leg) | São Paulo FC | - | Fluminense RJ | 1:0 (1:0) | ||
| 2nd (2nd leg) | Fluminense RJ | - | São Paulo FC | 3:1 (1:0) | ||
| 1st(1st leg): 15/05/2008 01:50 | 2nd (2nd leg): 22/05/2008 01:50 | Winner: Fluminense RJ | ||||
| 1st(1st leg) | San Lorenzo | - | LDU Quito | 1:1 (1:1) | ||
| 2nd (2nd leg) | LDU Quito | - | San Lorenzo | 5:3 (1:0, 1:1, 1:1) pso | ||
| 1st(1st leg): 15/05/2008 23:00 | 2nd (2nd leg): 22/05/2008 23:20 | Winner: LDU Quito | ||||
| 1st(1st leg) | CF América | - | Santos FC | 2:0 (1:0) | ||
| 2nd (2nd leg) | Santos FC | - | CF América | 1:0 (0:0) | ||
| 1st(1st leg): 16/05/2008 01:20 | 2nd (2nd leg): 23/05/2008 01:50 | Winner: CF América | ||||
