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| 1st(1st leg) | Fluminense RJ | - | Universidad Católica | 2:1 (2:0) | ||
| 2nd (2nd leg) | Universidad Católica | - | Fluminense RJ | 2:0 (1:0) | ||
| 1st(1st leg): 18/10/2005 | 2nd (2nd leg): 09/11/2005 | Winner: Universidad Católica | ||||
| 1st(1st leg) | Internacional | - | Boca Juniors | 1:0 (0:0) | ||
| 2nd (2nd leg) | Boca Juniors | - | Internacional | 4:1 (1:0) | ||
| 1st(1st leg): 19/10/2005 | 2nd (2nd leg): 10/11/2005 | Winner: Boca Juniors | ||||
| 1st(1st leg) | Corinthians SP | - | Pumas UNAM | 2:1 (1:0) | ||
| 2nd (2nd leg) | Pumas UNAM | - | Corinthians SP | 3:0 (0:0) | ||
| 1st(1st leg): 19/10/2005 | 2nd (2nd leg): 09/11/2005 | Winner: Pumas UNAM | ||||
| 1st(1st leg) | CF América | - | Vélez Sarsfield | 0:2 (0:1) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | CF América | 2:0 (0:0) | ||
| 1st(1st leg): 26/10/2005 | 2nd (2nd leg): 02/11/2005 | Winner: Vélez Sarsfield | ||||
