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| 1st(1st leg) | Mineros de Guayana | - | Carabobo FC | 3:0 (3:0) | ||
| 2nd (2nd leg) | Carabobo FC | - | Mineros de Guayana | 1:3 (0:2) | ||
| 1st(1st leg): 22/08/2006 | 2nd (2nd leg): 30/08/2006 | Winner: Mineros de Guayana | ||||
| 1st(1st leg) | LDU Quito | - | El Nacional | 2:3 (0:2) | ||
| 2nd (2nd leg) | El Nacional | - | LDU Quito | 1:1 (0:1) | ||
| 1st(1st leg): 22/08/2006 | 2nd (2nd leg): 29/08/2006 | Winner: El Nacional | ||||
| 1st(1st leg) | Central Español | - | Nacional | 0:1 (0:0) | ||
| 2nd (2nd leg) | Nacional | - | Central Español | 0:0 (0:0) | ||
| 1st(1st leg): 23/08/2006 | 2nd (2nd leg): 29/08/2006 | Winner: Nacional | ||||
| 1st(1st leg) | Libertad | - | Cerro Porteño | 3:1 (1:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Libertad | 0:1 (0:0) | ||
| 1st(1st leg): 23/08/2006 | 2nd (2nd leg): 29/08/2006 | Winner: Libertad | ||||
| 1st(1st leg) | Deportes Tolima | - | Independiente Medellín | 3:1 (1:1) | ||
| 2nd (2nd leg) | Independiente Medellín | - | Deportes Tolima | 1:1 (0:1) | ||
| 1st(1st leg): 23/08/2006 | 2nd (2nd leg): 29/08/2006 | Winner: Deportes Tolima | ||||
| 1st(1st leg) | Huachipato | - | Colo-Colo | 1:2 (1:1) | ||
| 2nd (2nd leg) | Colo-Colo | - | Huachipato | 5:3 (1:0, 1:2, 1:2) pso | ||
| 1st(1st leg): 24/08/2006 | 2nd (2nd leg): 31/08/2006 | Winner: Colo-Colo | ||||
| 1st(1st leg) | Coronel Bolognesi | - | Universidad San Martín | 1:0 (0:0) | ||
| 2nd (2nd leg) | Universidad San Martín | - | Coronel Bolognesi | 3:2 (2:1) | ||
| 1st(1st leg): 24/08/2006 | 2nd (2nd leg): 31/08/2006 | Winner: Coronel Bolognesi | ||||
| 1st(1st leg) | Universitario de Sucre | - | Bolívar | 2:2 (2:1) | ||
| 2nd (2nd leg) | Bolívar | - | Universitario de Sucre | 2:3 (1:2) | ||
| 1st(1st leg): 24/08/2006 | 2nd (2nd leg): 31/08/2006 | Winner: Universitario de Sucre | ||||
