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| 1st(1st leg) | Deportivo Quito | - | Tigre | 2:0 (0:0) | ||
| 2nd (2nd leg) | Tigre | - | Deportivo Quito | 4:0 (1:0) | ||
| 1st(1st leg): 25/09/2012 23:15 | 2nd (2nd leg): 26/10/2012 01:45 | Winner: Tigre | ||||
| 1st(1st leg) | Independiente | - | Liverpool | 2:1 (1:0) | ||
| 2nd (2nd leg) | Liverpool | - | Independiente | 1:2 (1:0) | ||
| 1st(1st leg): 26/09/2012 01:30 | 2nd (2nd leg): 25/10/2012 23:15 | Winner: Independiente | ||||
| 1st(1st leg) | Liga de Loja | - | São Paulo FC | 1:1 (1:1) | ||
| 2nd (2nd leg) | São Paulo FC | - | Liga de Loja | 0:0 (0:0) | ||
| 1st(1st leg): 27/09/2012 02:00 | 2nd (2nd leg): 25/10/2012 01:00 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Barcelona | - | Grêmio Porto Alegre | 0:1 (0:1) | ||
| 2nd (2nd leg) | Grêmio Porto Alegre | - | Barcelona | 2:1 (0:0) | ||
| 1st(1st leg): 27/09/2012 02:00 | 2nd (2nd leg): 25/10/2012 01:00 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | Colón de Santa Fe | - | Cerro Porteño | 1:2 (1:1) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Colón de Santa Fe | 2:1 (1:1) | ||
| 1st(1st leg): 28/09/2012 01:15 | 2nd (2nd leg): 23/10/2012 23:15 | Winner: Cerro Porteño | ||||
| 1st(1st leg) | Universidad de Chile | - | Emelec | 2:2 (1:2) | ||
| 2nd (2nd leg) | Emelec | - | Universidad de Chile | 0:1 (0:0) | ||
| 1st(1st leg): 02/10/2012 23:15 | 2nd (2nd leg): 26/10/2012 01:45 | Winner: Universidad de Chile | ||||
| 1st(1st leg) | Palmeiras | - | Millonarios | 3:1 (1:0) | ||
| 2nd (2nd leg) | Millonarios | - | Palmeiras | 3:0 (1:0) | ||
| 1st(1st leg): 03/10/2012 01:45 | 2nd (2nd leg): 24/10/2012 01:45 | Winner: Millonarios | ||||
| 1st(1st leg) | Universidad Católica | - | Atlético Goianiense | 2:0 (0:0) | ||
| 2nd (2nd leg) | Atlético Goianiense | - | Universidad Católica | 3:1 (2:1) | ||
| 1st(1st leg): 04/10/2012 00:15 | 2nd (2nd leg): 24/10/2012 22:30 | Winner: Universidad Católica | ||||
