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| 1st(1st leg) | Grêmio Porto Alegre | - | Millonarios | 1:0 (1:0) | ||
| 2nd (2nd leg) | Millonarios | - | Grêmio Porto Alegre | 3:1 (0:1) | ||
| 1st(1st leg): 30/10/2012 23:50 | 2nd (2nd leg): 16/11/2012 00:15 | Winner: Millonarios | ||||
| 1st(1st leg) | Universidad de Chile | - | São Paulo FC | 0:2 (0:2) | ||
| 2nd (2nd leg) | São Paulo FC | - | Universidad de Chile | 5:0 (3:0) | ||
| 1st(1st leg): 31/10/2012 23:50 | 2nd (2nd leg): 07/11/2012 23:50 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Cerro Porteño | - | Tigre | 1:0 (1:0) | ||
| 2nd (2nd leg) | Tigre | - | Cerro Porteño | 4:2 (2:0) | ||
| 1st(1st leg): 01/11/2012 22:15 | 2nd (2nd leg): 09/11/2012 00:45 | Winner: Tigre | ||||
| 1st(1st leg) | Independiente | - | Universidad Católica | 2:2 (1:1) | ||
| 2nd (2nd leg) | Universidad Católica | - | Independiente | 2:1 (2:1) | ||
| 1st(1st leg): 02/11/2012 00:45 | 2nd (2nd leg): 08/11/2012 22:15 | Winner: Universidad Católica | ||||
