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| 1st(1st leg) | Libertad | - | Fortaleza | 0:1 (0:1) | ||
| 2nd (2nd leg) | Fortaleza | - | Libertad | 1:1 (0:1) | ||
| 1st(1st leg): 01/08/2023 23:00 | 2nd (2nd leg): 08/08/2023 23:00 | Winner: Fortaleza | ||||
| 1st(1st leg) | Emelec | - | Defensa y Justicia | 1:2 (1:0) | ||
| 2nd (2nd leg) | Defensa y Justicia | - | Emelec | 1:0 (0:0) | ||
| 1st(1st leg): 02/08/2023 01:00 | 2nd (2nd leg): 09/08/2023 01:00 | Winner: Defensa y Justicia | ||||
| 1st(1st leg) | Corinthians SP | - | Newell's Old Boys | 2:1 (0:1) | ||
| 2nd (2nd leg) | Newell's Old Boys | - | Corinthians SP | 0:0 (0:0) | ||
| 1st(1st leg): 02/08/2023 01:30 | 2nd (2nd leg): 09/08/2023 01:30 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Botafogo - RJ | - | Guaraní | 2:1 (0:1) | ||
| 2nd (2nd leg) | Guaraní | - | Botafogo - RJ | 0:0 (0:0) | ||
| 1st(1st leg): 02/08/2023 23:00 | 2nd (2nd leg): 09/08/2023 23:00 | Winner: Botafogo - RJ | ||||
| 1st(1st leg) | Estudiantes | - | Goiás - GO | 3:0 (0:0) | ||
| 2nd (2nd leg) | Goiás - GO | - | Estudiantes | 0:2 (0:1) | ||
| 1st(1st leg): 02/08/2023 23:00 | 2nd (2nd leg): 09/08/2023 23:00 | Winner: Estudiantes | ||||
| 1st(1st leg) | San Lorenzo | - | São Paulo FC | 1:0 (0:0) | ||
| 2nd (2nd leg) | São Paulo FC | - | San Lorenzo | 2:0 (1:0) | ||
| 1st(1st leg): 03/08/2023 23:00 | 2nd (2nd leg): 10/08/2023 23:00 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Ñublense | - | LDU Quito | 0:1 (0:0) | ||
| 2nd (2nd leg) | LDU Quito | - | Ñublense | 4:3 (1:1, 2:3) pso | ||
| 1st(1st leg): 04/08/2023 01:00 | 2nd (2nd leg): 11/08/2023 01:00 | Winner: LDU Quito | ||||
| 1st(1st leg) | América - MG | - | Red Bull Bragantino | 1:1 (0:1) | ||
| 2nd (2nd leg) | Red Bull Bragantino | - | América - MG | 3:4 (2:2, 3:3) pso | ||
| 1st(1st leg): 04/08/2023 01:00 | 2nd (2nd leg): 11/08/2023 01:00 | Winner: América - MG | ||||
