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| 1st(1st leg) | CD Tenerife | - | Deportivo La Coruña | 0:6 (0:4) | ||
| 2nd (2nd leg) | Deportivo La Coruña | - | CD Tenerife | 2:1 (0:0) | ||
| 1st(1st leg): 10/05/2025 12:00 | 2nd (2nd leg): 18/05/2025 11:00 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | Valencia CF | - | FC Barcelona | 2:2 (1:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Valencia CF | 3:4 (3:0, 3:3, 3:3) pso | ||
| 1st(1st leg): 11/05/2025 11:00 | 2nd (2nd leg): 18/05/2025 11:00 | Winner: Valencia CF | ||||
| 1st(1st leg) | Real Madrid | - | Athletic Club | 1:1 (1:1) | ||
| 2nd (2nd leg) | Athletic Club | - | Real Madrid | 2:4 (0:1) | ||
| 1st(1st leg): 11/05/2025 11:00 | 2nd (2nd leg): 18/05/2025 11:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | UD Las Palmas | - | Real Betis | 1:3 (1:0) | ||
| 2nd (2nd leg) | Real Betis | - | UD Las Palmas | 2:2 (0:2) | ||
| 1st(1st leg): 11/05/2025 12:00 | 2nd (2nd leg): 18/05/2025 10:00 | Winner: Real Betis | ||||
