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| 1st(1st leg) | Atlético Madrid | - | FC Barcelona | 1:2 | ||
| 2nd (2nd leg) | FC Barcelona | - | Atlético Madrid | 0:0 | ||
| 1st(1st leg): 12/02/1986 | 2nd (2nd leg): 26/02/1986 | Winner: FC Barcelona | ||||
| 1st(1st leg) | CE Sabadell | - | Athletic Bilbao | 1:1 | ||
| 2nd (2nd leg) | Athletic Bilbao | - | CE Sabadell | 3:2 pso | ||
| 1st(1st leg): 12/02/1986 | 2nd (2nd leg): 26/02/1986 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | RC Celta | - | Real Madrid | 0:0 | ||
| 2nd (2nd leg) | Real Madrid | - | RC Celta | 4:0 | ||
| 1st(1st leg): 12/02/1986 | 2nd (2nd leg): 26/02/1986 | Winner: Real Madrid | ||||
| 1st(1st leg) | Castilla CF | - | Real Zaragoza | 2:1 | ||
| 2nd (2nd leg) | Real Zaragoza | - | Castilla CF | 7:0 | ||
| 1st(1st leg): 20/02/1986 | 2nd (2nd leg): 26/02/1986 | Winner: Real Zaragoza | ||||
