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| 1st(1st leg) | Real Zaragoza | - | Valencia CF | 2:1 (1:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Real Zaragoza | 1:3 (0:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 09/01/1990 | 2nd (2nd leg): 24/01/1990 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | Real Madrid | - | Real Valladolid | 3:0 (2:0) | ||
| 2nd (2nd leg) | Real Valladolid | - | Real Madrid | 1:0 (1:0) | ||
| 1st(1st leg): 10/01/1990 | 2nd (2nd leg): 23/01/1990 | Winner: Real Madrid | ||||
| 1st(1st leg) | Sporting Gijón | - | Cádiz CF | 0:0 (0:0) | ||
| 2nd (2nd leg) | Cádiz CF | - | Sporting Gijón | 2:1 (1:1) | ||
| 1st(1st leg): 10/01/1990 | 2nd (2nd leg): 25/01/1990 | Winner: Cádiz CF | ||||
| 1st(1st leg) | Real Sociedad | - | FC Barcelona | 0:1 (0:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Real Sociedad | 3:3 (1:2) | ||
| 1st(1st leg): 17/01/1990 | 2nd (2nd leg): 24/01/1990 | Winner: FC Barcelona | ||||
