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| 1st(1st leg) | Lleida Esportiu | - | Real Betis | 1:2 (0:2) | ||
| 2nd (2nd leg) | Real Betis | - | Lleida Esportiu | 2:2 (2:1) | ||
| 1st(1st leg): 06/12/2013 11:00 | 2nd (2nd leg): 18/12/2013 18:30 | Winner: Real Betis | ||||
| 1st(1st leg) | Villarreal CF | - | Elche CF | 2:2 (1:0) | ||
| 2nd (2nd leg) | Elche CF | - | Villarreal CF | 0:1 (0:0) | ||
| 1st(1st leg): 06/12/2013 15:00 | 2nd (2nd leg): 17/12/2013 19:00 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Algeciras CF | - | Real Sociedad | 1:1 (0:0) | ||
| 2nd (2nd leg) | Real Sociedad | - | Algeciras CF | 4:0 (1:0) | ||
| 1st(1st leg): 06/12/2013 17:00 | 2nd (2nd leg): 18/12/2013 18:30 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Racing Santander | - | Sevilla FC | 0:1 (0:1) | ||
| 2nd (2nd leg) | Sevilla FC | - | Racing Santander | 0:2 (0:0) | ||
| 1st(1st leg): 06/12/2013 19:00 | 2nd (2nd leg): 18/12/2013 20:30 | Winner: Racing Santander | ||||
| 1st(1st leg) | Real Valladolid | - | Rayo Vallecano | 0:0 (0:0) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Real Valladolid | 3:1 (1:1) | ||
| 1st(1st leg): 06/12/2013 21:00 | 2nd (2nd leg): 19/12/2013 18:30 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | FC Cartagena | - | FC Barcelona | 1:4 (1:2) | ||
| 2nd (2nd leg) | FC Barcelona | - | FC Cartagena | 3:0 (1:0) | ||
| 1st(1st leg): 06/12/2013 21:00 | 2nd (2nd leg): 17/12/2013 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | UE Sant Andreu | - | Atlético Madrid | 0:4 (0:2) | ||
| 2nd (2nd leg) | Atlético Madrid | - | UE Sant Andreu | 2:1 (0:1) | ||
| 1st(1st leg): 07/12/2013 15:00 | 2nd (2nd leg): 18/12/2013 18:30 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Girona FC | - | Getafe CF | 1:1 (1:1) | ||
| 2nd (2nd leg) | Getafe CF | - | Girona FC | 4:1 (3:0) | ||
| 1st(1st leg): 07/12/2013 17:00 | 2nd (2nd leg): 17/12/2013 19:00 | Winner: Getafe CF | ||||
| 1st(1st leg) | RC Celta | - | Athletic Club | 1:0 (0:0) | ||
| 2nd (2nd leg) | Athletic Club | - | RC Celta | 4:0 (2:0) | ||
| 1st(1st leg): 07/12/2013 19:00 | 2nd (2nd leg): 19/12/2013 20:30 | Winner: Athletic Club | ||||
| 1st(1st leg) | Recreativo Huelva | - | Levante UD | 1:0 (0:0) | ||
| 2nd (2nd leg) | Levante UD | - | Recreativo Huelva | 4:0 (3:0) | ||
| 1st(1st leg): 07/12/2013 21:00 | 2nd (2nd leg): 17/12/2013 19:00 | Winner: Levante UD | ||||
| 1st(1st leg) | Olímpic Xàtiva | - | Real Madrid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | Olímpic Xàtiva | 2:0 (2:0) | ||
| 1st(1st leg): 07/12/2013 21:00 | 2nd (2nd leg): 18/12/2013 20:30 | Winner: Real Madrid | ||||
| 1st(1st leg) | AD Alcorcón | - | Granada CF | 0:2 (0:1) | ||
| 2nd (2nd leg) | Granada CF | - | AD Alcorcón | 4:5 (0:1, 0:2, 0:2) pso | ||
| 1st(1st leg): 08/12/2013 11:00 | 2nd (2nd leg): 17/12/2013 21:00 | Winner: AD Alcorcón | ||||
| 1st(1st leg) | UD Las Palmas | - | UD Almería | 1:3 (0:3) | ||
| 2nd (2nd leg) | UD Almería | - | UD Las Palmas | 0:0 (0:0) | ||
| 1st(1st leg): 08/12/2013 16:00 | 2nd (2nd leg): 18/12/2013 18:30 | Winner: UD Almería | ||||
| 1st(1st leg) | Gimnàstic de Tarragona | - | Valencia CF | 0:0 (0:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Gimnàstic de Tarragona | 1:0 (1:0) | ||
| 1st(1st leg): 08/12/2013 16:00 | 2nd (2nd leg): 19/12/2013 18:30 | Winner: Valencia CF | ||||
| 1st(1st leg) | Real Jaén | - | Espanyol Barcelona | 2:2 (0:1) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Real Jaén | 2:0 (1:0) | ||
| 1st(1st leg): 08/12/2013 18:00 | 2nd (2nd leg): 19/12/2013 18:30 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Málaga CF | - | CA Osasuna | 3:3 (2:0) | ||
| 2nd (2nd leg) | CA Osasuna | - | Málaga CF | 1:1 (1:0) | ||
| 1st(1st leg): 08/12/2013 20:00 | 2nd (2nd leg): 17/12/2013 19:00 | Winner: CA Osasuna | ||||
