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| 1st(1st leg) | Espanyol Barcelona | - | Real Madrid | 0:1 (0:1) | ||
| 2nd (2nd leg) | Real Madrid | - | Espanyol Barcelona | 1:0 (1:0) | ||
| 1st(1st leg): 21/01/2014 20:00 | 2nd (2nd leg): 28/01/2014 20:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | Real Sociedad | - | Racing Santander | 3:1 (2:0) | ||
| 2nd (2nd leg) | Racing Santander | - | Real Sociedad | 0:3 dec. | ||
| 1st(1st leg): 22/01/2014 19:00 | 2nd (2nd leg): 30/01/2014 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Levante UD | - | FC Barcelona | 1:4 (1:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | Levante UD | 5:1 (2:1) | ||
| 1st(1st leg): 22/01/2014 21:00 | 2nd (2nd leg): 29/01/2014 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Athletic Club | 1:0 (1:0) | ||
| 2nd (2nd leg) | Athletic Club | - | Atlético Madrid | 1:2 (1:0) | ||
| 1st(1st leg): 23/01/2014 20:00 | 2nd (2nd leg): 29/01/2014 19:00 | Winner: Atlético Madrid | ||||
