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| 1st(1st leg) | SD Amorebieta | - | RB Linense | 1:1 | ||
| 2nd (2nd leg) | RB Linense | - | SD Amorebieta | 2:1 | ||
| 1st(1st leg): 19/05/2012 17:30 | 2nd (2nd leg): 27/05/2012 18:00 | Winner: RB Linense | ||||
| 1st(1st leg) | Huracán CF | - | Lucena CF | 0:0 | ||
| 2nd (2nd leg) | Lucena CF | - | Huracán CF | 4:2 pso | ||
| 1st(1st leg): 20/05/2012 17:00 | 2nd (2nd leg): 27/05/2012 17:30 | Winner: Lucena CF | ||||
| 1st(1st leg) | CD Lugo | - | SD Eibar | 1:0 | ||
| 2nd (2nd leg) | SD Eibar | - | CD Lugo | 0:0 | ||
| 1st(1st leg): 20/05/2012 17:00 | 2nd (2nd leg): 26/05/2012 19:15 | Winner: CD Lugo | ||||
| 1st(1st leg) | CF Badalona | - | CD Tenerife | 1:1 | ||
| 2nd (2nd leg) | CD Tenerife | - | CF Badalona | 3:1 | ||
| 1st(1st leg): 20/05/2012 17:30 | 2nd (2nd leg): 27/05/2012 17:30 | Winner: CD Tenerife | ||||
| 1st(1st leg) | Albacete | - | Orihuela CF | 1:1 | ||
| 2nd (2nd leg) | Orihuela CF | - | Albacete | 0:1 | ||
| 1st(1st leg): 20/05/2012 19:00 | 2nd (2nd leg): 26/05/2012 20:00 | Winner: Albacete | ||||
| 1st(1st leg) | Real Jaén | - | SD Ponferradina | 2:1 | ||
| 2nd (2nd leg) | SD Ponferradina | - | Real Jaén | 2:0 | ||
| 1st(1st leg): 20/05/2012 19:00 | 2nd (2nd leg): 27/05/2012 19:00 | Winner: SD Ponferradina | ||||
