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| 1st(1st leg) | Lucena CF | - | SD Ponferradina | 2:1 | ||
| 2nd (2nd leg) | SD Ponferradina | - | Lucena CF | 3:0 | ||
| 1st(1st leg): 02/06/2012 17:30 | 2nd (2nd leg): 09/06/2012 20:00 | Winner: SD Ponferradina | ||||
| 1st(1st leg) | CD Lugo | - | Atlético Baleares | 3:1 | ||
| 2nd (2nd leg) | Atlético Baleares | - | CD Lugo | 0:0 | ||
| 1st(1st leg): 03/06/2012 11:00 | 2nd (2nd leg): 10/06/2012 11:00 | Winner: CD Lugo | ||||
| 1st(1st leg) | RB Linense | - | CD Tenerife | 0:1 | ||
| 2nd (2nd leg) | CD Tenerife | - | RB Linense | 3:2 | ||
| 1st(1st leg): 03/06/2012 18:00 | 2nd (2nd leg): 10/06/2012 12:00 | Winner: CD Tenerife | ||||
| 1st(1st leg) | Albacete | - | Cádiz CF | 0:0 | ||
| 2nd (2nd leg) | Cádiz CF | - | Albacete | 4:3 pso | ||
| 1st(1st leg): 03/06/2012 19:00 | 2nd (2nd leg): 09/06/2012 20:30 | Winner: Cádiz CF | ||||
