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| 1st(1st leg) | UD Las Palmas B | - | La Hoya Lorca CF | 1:2 (1:1) | ||
| 2nd (2nd leg) | La Hoya Lorca CF | - | UD Las Palmas B | 0:1 (0:0) | ||
| 1st(1st leg): 18/05/2014 10:30 | 2nd (2nd leg): 25/05/2014 18:30 | Winner: La Hoya Lorca CF | ||||
| 1st(1st leg) | FC Cartagena | - | Real Avilés | 1:3 (0:1) | ||
| 2nd (2nd leg) | Real Avilés | - | FC Cartagena | 2:0 (1:0) | ||
| 1st(1st leg): 18/05/2014 11:00 | 2nd (2nd leg): 25/05/2014 17:45 | Winner: Real Avilés | ||||
| 1st(1st leg) | CD Guijuelo | - | CD Leganés | 0:0 (0:0) | ||
| 2nd (2nd leg) | CD Leganés | - | CD Guijuelo | 1:0 (0:0) | ||
| 1st(1st leg): 18/05/2014 17:30 | 2nd (2nd leg): 25/05/2014 11:00 | Winner: CD Leganés | ||||
| 1st(1st leg) | CD Toledo | - | Lleida Esportiu | 1:1 (1:0) | ||
| 2nd (2nd leg) | Lleida Esportiu | - | CD Toledo | 2:1 (0:1) | ||
| 1st(1st leg): 18/05/2014 17:30 | 2nd (2nd leg): 24/05/2014 17:30 | Winner: Lleida Esportiu | ||||
| 1st(1st leg) | Gimnàstic de Tarragona | - | Racing Ferrol | 2:0 (2:0) | ||
| 2nd (2nd leg) | Racing Ferrol | - | Gimnàstic de Tarragona | 0:0 (0:0) | ||
| 1st(1st leg): 18/05/2014 18:00 | 2nd (2nd leg): 24/05/2014 16:45 | Winner: Gimnàstic de Tarragona | ||||
| 1st(1st leg) | Cádiz CF | - | CE L'Hospitalet | 0:0 (0:0) | ||
| 2nd (2nd leg) | CE L'Hospitalet | - | Cádiz CF | 2:1 (0:0) | ||
| 1st(1st leg): 18/05/2014 18:00 | 2nd (2nd leg): 25/05/2014 11:00 | Winner: CE L'Hospitalet | ||||
