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| 1st(1st leg) | Lleida Esportiu | - | CD Leganés | 0:0 (0:0) | ||
| 2nd (2nd leg) | CD Leganés | - | Lleida Esportiu | 1:0 (0:0) aet | ||
| 1st(1st leg): 01/06/2014 17:00 | 2nd (2nd leg): 08/06/2014 11:00 | Winner: CD Leganés | ||||
| 1st(1st leg) | Real Avilés | - | UE Llagostera | 2:0 (1:0) | ||
| 2nd (2nd leg) | UE Llagostera | - | Real Avilés | 3:0 (2:0) | ||
| 1st(1st leg): 01/06/2014 17:45 | 2nd (2nd leg): 08/06/2014 18:00 | Winner: UE Llagostera | ||||
| 1st(1st leg) | Gimnàstic de Tarragona | - | Sestao River | 1:1 (0:0) | ||
| 2nd (2nd leg) | Sestao River | - | Gimnàstic de Tarragona | 1:2 (1:0) | ||
| 1st(1st leg): 01/06/2014 18:00 | 2nd (2nd leg): 07/06/2014 20:00 | Winner: Gimnàstic de Tarragona | ||||
| 1st(1st leg) | La Hoya Lorca CF | - | CE L'Hospitalet | 2:2 (1:1) | ||
| 2nd (2nd leg) | CE L'Hospitalet | - | La Hoya Lorca CF | 0:0 (0:0) | ||
| 1st(1st leg): 01/06/2014 18:30 | 2nd (2nd leg): 08/06/2014 11:00 | Winner: CE L'Hospitalet | ||||
