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| 12/02/2022 | 15:00 | Motherwell FC | - | Aberdeen FC | 2:1 (2:1) | |
| 15:00 | Heart of Midlothian | - | Livingston FC | 4:3 (0:0, 0:0, 0:0) pso | ||
| 15:00 | Partick Thistle | - | Dundee United | 0:1 (0:1) | ||
| 15:00 | St. Mirren FC | - | Kelty Hearts | 4:0 (1:0) | ||
| 17:30 | Annan Athletic | - | Rangers FC | 0:3 (0:3) | ||
| 13/02/2022 | 12:30 | Arbroath FC | - | Hibernian FC | 1:3 (1:1) | |
| 16:00 | Celtic FC | - | Raith Rovers | 4:0 (1:0) | ||
| 14/02/2022 | 19:45 | Peterhead FC | - | Dundee FC | 0:3 (0:1) |
