Copa Libertadores   M. W D L goals
  at home 3 2 1 0 3 : 1
  Away 3 1 1 1 4 : 4
  6 3 2 1 7 : 5
overall   M. W D L goals
  at home 3 2 1 0 3 : 1
  Away 3 1 1 1 4 : 4
  Neutral Place 0 0 0 0 0 : 0
  6 3 2 1 7 : 5
Copa Libertadores
2021 Group 3 Boca Juniors - Barcelona 0:0 (0:0)
2021 Group 3 Barcelona - Boca Juniors 1:0 (0:0)
2013 Group 1 Boca Juniors - Barcelona 1:0 (1:0)
2013 Group 1 Barcelona - Boca Juniors 1:2 (0:0)
2003 Group 7 Barcelona - Boca Juniors 2:2 (0:0)
2003 Group 7 Boca Juniors - Barcelona 2:1 (1:0)

For games that were decided on penalties the score after 120 minutes will be included in the ranking