| Champions League | M. | W | D | L | goals | |||
| at home | 2 | 0 | 2 | 0 | 1 | : | 1 | |
| Away | 2 | 0 | 0 | 2 | 0 | : | 4 | |
| ∑ | 4 | 0 | 2 | 2 | 1 | : | 5 | |
| Europa League | M. | W | D | L | goals | |||
| at home | 1 | 1 | 0 | 0 | 2 | : | 1 | |
| Away | 1 | 0 | 1 | 0 | 0 | : | 0 | |
| ∑ | 2 | 1 | 1 | 0 | 2 | : | 1 | |
| overall | M. | W | D | L | goals | |||
| at home | 3 | 1 | 2 | 0 | 3 | : | 2 | |
| Away | 3 | 0 | 1 | 2 | 0 | : | 4 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 6 | 1 | 3 | 2 | 3 | : | 6 | |
| Europa League | |||||
| 2020/2021 | Semi-finals | Arsenal FC | - | Villarreal CF | 0:0 (0:0) |
| 2020/2021 | Semi-finals | Villarreal CF | - | Arsenal FC | 2:1 (2:0) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Spain 
![Villarreal CF [Women]](https://s.hs-data.com/bilder/wappen/mini/32305.gif?fallback=png "Villarreal CF [Women]"){kind=small}
![Villarreal CF [Youth]](https://s.hs-data.com/bilder/wappen/mini/20530.gif?fallback=png "Villarreal CF [Youth]"){kind=small}
![Villarreal CF [Youth B]](https://s.hs-data.com/bilder/wappen/mini/25229.gif?fallback=png "Villarreal CF [Youth B]"){kind=small}
![Villarreal CF [Youth B Women]](https://s.hs-data.com/bilder/wappen/mini/36005.gif?fallback=png "Villarreal CF [Youth B Women]"){kind=small}
![Villarreal CF [Youth C]](https://s.hs-data.com/bilder/wappen/mini/39111.gif?fallback=png "Villarreal CF [Youth C]"){kind=small}
