| Champions League | M. | W | D | L | goals | |||
| at home | 1 | 0 | 1 | 0 | 2 | : | 2 | |
| Away | 1 | 1 | 0 | 0 | 3 | : | 2 | |
| ∑ | 2 | 1 | 1 | 0 | 5 | : | 4 | |
| overall | M. | W | D | L | goals | |||
| at home | 1 | 0 | 1 | 0 | 2 | : | 2 | |
| Away | 1 | 1 | 0 | 0 | 3 | : | 2 | |
| Neutral Place | 0 | 0 | 0 | 0 | 0 | : | 0 | |
| ∑ | 2 | 1 | 1 | 0 | 5 | : | 4 | |
| Champions League | |||||
| 2021/2022 | Group F | Atalanta | - | Villarreal CF | 2:3 (0:2) |
| 2021/2022 | Group F | Villarreal CF | - | Atalanta | 2:2 (1:1) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
Spain 
![Villarreal CF [Women]](https://s.hs-data.com/bilder/wappen/mini/32305.gif?fallback=png "Villarreal CF [Women]"){kind=small}
![Villarreal CF [Youth]](https://s.hs-data.com/bilder/wappen/mini/20530.gif?fallback=png "Villarreal CF [Youth]"){kind=small}
![Villarreal CF [Youth B]](https://s.hs-data.com/bilder/wappen/mini/25229.gif?fallback=png "Villarreal CF [Youth B]"){kind=small}
![Villarreal CF [Youth B Women]](https://s.hs-data.com/bilder/wappen/mini/36005.gif?fallback=png "Villarreal CF [Youth B Women]"){kind=small}
![Villarreal CF [Youth C]](https://s.hs-data.com/bilder/wappen/mini/39111.gif?fallback=png "Villarreal CF [Youth C]"){kind=small}
