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| 1st(1st leg) | River Plate | - | Cruzeiro | 0:0 (0:0) | ||
| 2nd (2nd leg) | Cruzeiro | - | River Plate | 2:4 (0:0, 0:0) pso | ||
| 1st(1st leg): 23/07/2019 23:15 | 2nd (2nd leg): 30/07/2019 23:15 | Winner: River Plate | ||||
| 1st(1st leg) | Godoy Cruz | - | Palmeiras | 2:2 (2:1) | ||
| 2nd (2nd leg) | Palmeiras | - | Godoy Cruz | 4:0 (0:0) | ||
| 1st(1st leg): 24/07/2019 01:30 | 2nd (2nd leg): 31/07/2019 01:30 | Winner: Palmeiras | ||||
| 1st(1st leg) | LDU Quito | - | Club Olimpia | 3:1 (1:0) | ||
| 2nd (2nd leg) | Club Olimpia | - | LDU Quito | 1:1 (1:1) | ||
| 1st(1st leg): 24/07/2019 01:30 | 2nd (2nd leg): 31/07/2019 01:30 | Winner: LDU Quito | ||||
| 1st(1st leg) | Nacional | - | Internacional | 0:1 (0:0) | ||
| 2nd (2nd leg) | Internacional | - | Nacional | 2:0 (1:0) | ||
| 1st(1st leg): 24/07/2019 23:15 | 2nd (2nd leg): 31/07/2019 23:15 | Winner: Internacional | ||||
| 1st(1st leg) | San Lorenzo | - | Cerro Porteño | 0:0 (0:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | San Lorenzo | 2:1 (0:1) | ||
| 1st(1st leg): 24/07/2019 23:15 | 2nd (2nd leg): 31/07/2019 23:15 | Winner: Cerro Porteño | ||||
| 1st(1st leg) | Emelec | - | Flamengo RJ | 2:0 (1:0) | ||
| 2nd (2nd leg) | Flamengo RJ | - | Emelec | 4:2 (2:0, 2:0) pso | ||
| 1st(1st leg): 25/07/2019 01:30 | 2nd (2nd leg): 01/08/2019 01:30 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Athletico Paranaense | - | Boca Juniors | 0:1 (0:0) | ||
| 2nd (2nd leg) | Boca Juniors | - | Athletico Paranaense | 2:0 (0:0) | ||
| 1st(1st leg): 25/07/2019 01:30 | 2nd (2nd leg): 01/08/2019 01:30 | Winner: Boca Juniors | ||||
| 1st(1st leg) | Grêmio Porto Alegre | - | Libertad | 2:0 (0:0) | ||
| 2nd (2nd leg) | Libertad | - | Grêmio Porto Alegre | 0:3 (0:3) | ||
| 1st(1st leg): 26/07/2019 01:30 | 2nd (2nd leg): 02/08/2019 01:30 | Winner: Grêmio Porto Alegre | ||||
