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| 1st(1st leg) | Belgrano de Córdoba | - | Vélez Sarsfield | 1:0 (1:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Belgrano de Córdoba | 2:0 (1:0) | ||
| 1st(1st leg): 14/08/2013 01:30 | 2nd (2nd leg): 30/08/2013 01:50 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | Racing Club | - | Lanús | 1:2 (0:2) | ||
| 2nd (2nd leg) | Lanús | - | Racing Club | 2:0 (1:0) | ||
| 1st(1st leg): 15/08/2013 01:15 | 2nd (2nd leg): 28/08/2013 23:30 | Winner: Lanús | ||||
| 1st(1st leg) | Sport Recife - PE | - | Náutico - PE | 2:0 (2:0) | ||
| 2nd (2nd leg) | Náutico - PE | - | Sport Recife - PE | 1:3 (1:0, 2:0, 2:0) pso | ||
| 1st(1st leg): 20/08/2013 23:30 | 2nd (2nd leg): 29/08/2013 01:50 | Winner: Sport Recife - PE | ||||
| 1st(1st leg) | Universidad Católica | - | Emelec | 4:0 (2:0) | ||
| 2nd (2nd leg) | Emelec | - | Universidad Católica | 2:3 (0:1) | ||
| 1st(1st leg): 21/08/2013 00:15 | 2nd (2nd leg): 27/08/2013 23:30 | Winner: Universidad Católica | ||||
| 1st(1st leg) | Guaraní | - | Atlético Nacional | 0:2 (0:1) | ||
| 2nd (2nd leg) | Atlético Nacional | - | Guaraní | 0:0 (0:0) | ||
| 1st(1st leg): 21/08/2013 00:15 | 2nd (2nd leg): 28/08/2013 02:00 | Winner: Atlético Nacional | ||||
| 1st(1st leg) | La Equidad | - | Cobreloa | 0:0 (0:0) | ||
| 2nd (2nd leg) | Cobreloa | - | La Equidad | 1:1 (1:1) | ||
| 1st(1st leg): 21/08/2013 02:30 | 2nd (2nd leg): 29/08/2013 23:30 | Winner: La Equidad | ||||
| 1st(1st leg) | Itagüi Ditaires | - | River Plate | 1:0 (0:0) | ||
| 2nd (2nd leg) | River Plate | - | Itagüi Ditaires | 0:0 (0:0) | ||
| 1st(1st leg): 21/08/2013 22:00 | 2nd (2nd leg): 28/08/2013 23:30 | Winner: Itagüi Ditaires | ||||
| 1st(1st leg) | Libertad | - | Mineros de Guayana | 2:0 (2:0) | ||
| 2nd (2nd leg) | Mineros de Guayana | - | Libertad | 1:2 (1:2) | ||
| 1st(1st leg): 22/08/2013 00:15 | 2nd (2nd leg): 29/08/2013 02:00 | Winner: Libertad | ||||
| 1st(1st leg) | Vitória - BA | - | Coritiba - PR | 1:0 (0:0) | ||
| 2nd (2nd leg) | Coritiba - PR | - | Vitória - BA | 4:3 (0:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 22/08/2013 01:50 | 2nd (2nd leg): 28/08/2013 01:50 | Winner: Coritiba - PR | ||||
| 1st(1st leg) | Criciúma - SC | - | Ponte Preta | 1:2 (0:1) | ||
| 2nd (2nd leg) | Ponte Preta | - | Criciúma - SC | 0:0 (0:0) | ||
| 1st(1st leg): 22/08/2013 01:50 | 2nd (2nd leg): 27/08/2013 23:30 | Winner: Ponte Preta | ||||
| 1st(1st leg) | Universidad de Chile | - | Club Social y Deportivo Independiente José Terán | 1:1 (1:0) | ||
| 2nd (2nd leg) | Club Social y Deportivo Independiente José Terán | - | Universidad de Chile | 1:3 (1:1) | ||
| 1st(1st leg): 22/08/2013 02:30 | 2nd (2nd leg): 29/08/2013 21:00 | Winner: Universidad de Chile | ||||
| 1st(1st leg) | San Lorenzo | - | River Plate | 0:1 (0:1) | ||
| 2nd (2nd leg) | River Plate | - | San Lorenzo | 0:0 (0:0) | ||
| 1st(1st leg): 22/08/2013 23:30 | 2nd (2nd leg): 06/09/2013 01:15 | Winner: River Plate | ||||
| 1st(1st leg) | Liga de Loja | - | Club Nacional | 0:0 (0:0) | ||
| 2nd (2nd leg) | Club Nacional | - | Liga de Loja | 0:1 (0:1) | ||
| 1st(1st leg): 22/08/2013 23:40 | 2nd (2nd leg): 29/08/2013 23:30 | Winner: Liga de Loja | ||||
| 1st(1st leg) | Deportivo Pasto | - | Colo-Colo | 1:0 (1:0) | ||
| 2nd (2nd leg) | Colo-Colo | - | Deportivo Pasto | 0:2 (0:2) | ||
| 1st(1st leg): 23/08/2013 01:50 | 2nd (2nd leg): 29/08/2013 02:00 | Winner: Deportivo Pasto | ||||
| 1st(1st leg) | Portuguesa - SP | - | Bahia - BA | 1:2 (0:1) | ||
| 2nd (2nd leg) | Bahia - BA | - | Portuguesa - SP | 0:0 (0:0) | ||
| 1st(1st leg): 23/08/2013 01:50 | 2nd (2nd leg): 29/08/2013 01:50 | Winner: Bahia - BA | ||||
