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| 1st(1st leg) | Athletic Bilbao | - | FC Barcelona | 0:0 (0:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | Athletic Bilbao | 0:1 (0:1) | ||
| 1st(1st leg): 10/05/2023 17:00 | 2nd (2nd leg): 14/05/2023 15:00 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Valencia CF | - | Real Betis | 1:3 (1:2) | ||
| 2nd (2nd leg) | Real Betis | - | Valencia CF | 1:2 (0:2) | ||
| 1st(1st leg): 10/05/2023 18:30 | 2nd (2nd leg): 14/05/2023 18:00 | Winner: Real Betis | ||||
| 1st(1st leg) | Atlético Madrid | - | Real Madrid | 0:2 (0:1) | ||
| 2nd (2nd leg) | Real Madrid | - | Atlético Madrid | 2:2 (0:2, 0:2) aet | ||
| 1st(1st leg): 10/05/2023 18:30 | 2nd (2nd leg): 14/05/2023 15:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | UD Las Palmas | - | RC Celta | 5:0 (2:0) | ||
| 2nd (2nd leg) | RC Celta | - | UD Las Palmas | 3:4 (0:2) | ||
| 1st(1st leg): 10/05/2023 19:00 | 2nd (2nd leg): 14/05/2023 10:00 | Winner: UD Las Palmas | ||||
