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| 1st(1st leg) | Real Madrid | - | Valencia CF | 2:0 (1:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Real Madrid | 1:1 (0:1) | ||
| 1st(1st leg): 15/01/2013 20:00 | 2nd (2nd leg): 23/01/2013 20:30 | Winner: Real Madrid | ||||
| 1st(1st leg) | Real Zaragoza | - | Sevilla FC | 0:0 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Real Zaragoza | 4:0 (2:0) | ||
| 1st(1st leg): 16/01/2013 18:30 | 2nd (2nd leg): 23/01/2013 18:30 | Winner: Sevilla FC | ||||
| 1st(1st leg) | FC Barcelona | - | Málaga CF | 2:2 (2:1) | ||
| 2nd (2nd leg) | Málaga CF | - | FC Barcelona | 2:4 (1:1) | ||
| 1st(1st leg): 16/01/2013 20:30 | 2nd (2nd leg): 24/01/2013 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Real Betis | 2:0 (2:0) | ||
| 2nd (2nd leg) | Real Betis | - | Atlético Madrid | 1:1 (0:1) | ||
| 1st(1st leg): 17/01/2013 21:00 | 2nd (2nd leg): 24/01/2013 19:00 | Winner: Atlético Madrid | ||||
