| 1. Round | 03/08/2013 | Southend United | - | Plymouth Argyle | 1:0 | ||||
| 2. Round | 10/08/2013 | Plymouth Argyle | - | Fleetwood Town | 0:2 | ||||
| 4. Round | 24/08/2013 | Plymouth Argyle | - | Rochdale AFC | 1:0 | ||||
| 7. Round | 14/09/2013 | Plymouth Argyle | - | Wycombe Wanderers | 0:3 | ||||
| 12. Round | 19/10/2013 | Hartlepool United | - | Plymouth Argyle | 1:0 | ||||
| 13. Round | 22/10/2013 | Plymouth Argyle | - | Newport County | 0:0 |
England