| 2. Round | 18/08/2023 | RCD Mallorca | - | Villarreal CF | 0:1 |  |
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| 3. Round | 27/08/2023 | Villarreal CF | - | FC Barcelona | 3:4 | ||||
| 4. Round | 01/09/2023 | Cádiz CF | - | Villarreal CF | 3:1 | ||||
| 5. Round | 17/09/2023 | Villarreal CF | - | UD Almería | 2:1 | ||||
| 7. Round | 27/09/2023 | Villarreal CF | - | Girona FC | 1:2 | |
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| 8. Round | 30/09/2023 | Getafe CF | - | Villarreal CF | 0:0 | ||||
| 9. Round | 08/10/2023 | Villarreal CF | - | UD Las Palmas | 1:2 | ||||
| 10. Round | 22/10/2023 | Villarreal CF | - | CD Alavés | 1:1 | ||||
| 13. Round | 12/11/2023 | Atlético Madrid | - | Villarreal CF | 3:1 | ||||
| 14. Round | 26/11/2023 | Villarreal CF | - | CA Osasuna | 3:1 | ||||
| 15. Round | 03/12/2023 | Sevilla FC | - | Villarreal CF | 1:1 | ||||
| 16. Round | 09/12/2023 | Villarreal CF | - | Real Sociedad | 0:3 | ||||
| 17. Round | 17/12/2023 | Real Madrid | - | Villarreal CF | 4:1 | ||||
| 19. Round | 02/01/2024 | Valencia CF | - | Villarreal CF | 3:1 |
England
