| 1. Round | 11/08/2024 | Sheffield Wednesday | - | Plymouth Argyle | 4:0 | ||||
| 2. Round | 17/08/2024 | Plymouth Argyle | - | Hull City | 1:1 | ||||
| 3. Round | 24/08/2024 | Queens Park Rangers | - | Plymouth Argyle | 1:1 | ||||
| 5. Round | 14/09/2024 | Plymouth Argyle | - | Sunderland AFC | 3:2 | ||||
| 7. Round | 27/09/2024 | Plymouth Argyle | - | Luton Town | 3:1 | ||||
| 20. Round | 10/12/2024 | Plymouth Argyle | - | Swansea City | 1:2 | ||||
| 21. Round | 14/12/2024 | Sheffield United | - | Plymouth Argyle | 2:0 | ||||
| 22. Round | 21/12/2024 | Plymouth Argyle | - | Middlesbrough FC | 3:3 | ||||
| 23. Round | 26/12/2024 | Coventry City | - | Plymouth Argyle | 4:0 | ||||
| 24. Round | 29/12/2024 | Oxford United | - | Plymouth Argyle | 2:0 | ||||
| 25. Round | 01/01/2025 | Plymouth Argyle | - | Bristol City | 2:2 | ||||
| 26. Round | 04/01/2025 | Stoke City | - | Plymouth Argyle | 0:0 | ||||
| 19. Round | 14/01/2025 | Plymouth Argyle | - | Oxford United | 1:1 |
Zimbabwe
England 
