| 1. Round | 04/09/2021 | FC Barcelona [Women] | - | UDG Tenerife Sur [Women] | 5:0 |  |
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| 2. Round | 11/09/2021 | Real Betis [Women] | - | FC Barcelona [Women] | 0:5 | ||||
| 3. Round | 25/09/2021 | FC Barcelona [Women] | - | Valencia CF [Women] | 8:0 | ||||
| 4. Round | 29/09/2021 | Villarreal CF [Women] | - | FC Barcelona [Women] | 0:8 | ||||
| 5. Round | 02/10/2021 | FC Barcelona [Women] | - | CD Alavés [Women] | 9:1 | |
Spain