| 9. Round | 20/11/2022 | FC Barcelona [Women] | - | CD Alavés [Women] | 8:0 | ||||
| 12. Round | 10/12/2022 | FC Barcelona [Women] | - | Alhama CF [Women] | 4:0 |  |
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| 14. Round | 07/01/2023 | FC Barcelona [Women] | - | Sevilla FC [Women] | 4:0 | ||||
| 19. Round | 11/02/2023 | CD Alavés [Women] | - | FC Barcelona [Women] | 0:4 | ||||
| 22. Round | 17/03/2023 | FC Barcelona [Women] | - | Valencia CF [Women] | 5:1 | ||||
| 24. Round | 02/04/2023 | Alhama CF [Women] | - | FC Barcelona [Women] | 0:2 |  |
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| 25. Round | 15/04/2023 | FC Barcelona [Women] | - | Atlético Madrid [Women] | 4:0 | ||||
| 27. Round | 30/04/2023 | FC Barcelona [Women] | - | Sporting de Huelva [Women] | 3:0 | ||||
| 28. Round | 06/05/2023 | Real Sociedad [Women] | - | FC Barcelona [Women] | 2:5 | ||||
| 26. Round | 10/05/2023 | Sevilla FC [Women] | - | FC Barcelona [Women] | 1:1 |
Spain