| 4. Round | 24/08/2013 | Oldham Athletic | - | Port Vale FC | 3:1 | ||||
| 21. Round | 21/12/2013 | Milton Keynes Dons | - | Port Vale FC | 3:0 | ||||
| 22. Round | 26/12/2013 | Port Vale FC | - | Notts County | 2:1 | ||||
| 23. Round | 29/12/2013 | Port Vale FC | - | Rotherham United | 2:0 |  |
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| 24. Round | 01/01/2014 | Preston North End | - | Port Vale FC | 3:2 | ||||
| 27. Round | 18/01/2014 | Port Vale FC | - | Oldham Athletic | 1:0 | ||||
| 35. Round | 08/03/2014 | Port Vale FC | - | Carlisle United | 2:1 | ||||
| 44. Round | 21/04/2014 | Rotherham United | - | Port Vale FC | 1:0 | ||||
| 45. Round | 25/04/2014 | Port Vale FC | - | Sheffield United | 1:2 | ||||
| 46. Round | 03/05/2014 | Peterborough United | - | Port Vale FC | 0:0 |
England