| 5. Round | 18/09/2021 | Liverpool FC | - | Crystal Palace | 3:0 | ||||
| 6. Round | 25/09/2021 | Brentford FC | - | Liverpool FC | 3:3 |  |
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| 7. Round | 03/10/2021 | Liverpool FC | - | Manchester City | 2:2 | ||||
| 9. Round | 24/10/2021 | Manchester United | - | Liverpool FC | 0:5 | ||||
| 10. Round | 30/10/2021 | Liverpool FC | - | Brighton & Hove Albion | 2:2 | ||||
| 21. Round | 02/01/2022 | Chelsea FC | - | Liverpool FC | 2:2 | ||||
| 22. Round | 16/01/2022 | Liverpool FC | - | Brentford FC | 3:0 | ||||
| 23. Round | 23/01/2022 | Crystal Palace | - | Liverpool FC | 1:3 | ||||
| 24. Round | 10/02/2022 | Liverpool FC | - | Leicester City | 2:0 | ||||
| 19. Round | 23/02/2022 | Liverpool FC | - | Leeds United | 6:0 | ||||
| 28. Round | 05/03/2022 | Liverpool FC | - | West Ham United | 1:0 | ||||
| 27. Round | 16/03/2022 | Arsenal FC | - | Liverpool FC | 0:2 | ||||
| 31. Round | 02/04/2022 | Liverpool FC | - | Watford FC | 2:0 | ||||
| 33. Round | 10/05/2022 | Aston Villa | - | Liverpool FC | 1:2 | ||||
| 37. Round | 17/05/2022 | Southampton FC | - | Liverpool FC | 1:2 |
England
