| 1. Round | 14/08/2022 | Racing Santander | - | Villarreal CF B | 0:2 | ||||
| 2. Round | 19/08/2022 | Villarreal CF B | - | SD Eibar | 2:2 |  |
|||
| 10. Round | 12/10/2022 | Villarreal CF B | - | SD Ponferradina | 2:2 | ||||
| 11. Round | 15/10/2022 | Real Zaragoza | - | Villarreal CF B | 2:1 | |
|||
| 12. Round | 22/10/2022 | Villarreal CF B | - | FC Andorra | 1:0 | ||||
| 13. Round | 30/10/2022 | Albacete | - | Villarreal CF B | 0:0 | ||||
| 14. Round | 02/11/2022 | Villarreal CF B | - | Real Oviedo | 2:1 | ||||
| 15. Round | 05/11/2022 | SD Huesca | - | Villarreal CF B | 1:0 | ||||
| 16. Round | 20/11/2022 | Villarreal CF B | - | UD Ibiza | 1:0 | ||||
| 17. Round | 26/11/2022 | CD Alavés | - | Villarreal CF B | 2:0 | ||||
| 21. Round | 17/12/2022 | Villarreal CF B | - | UD Las Palmas | 0:1 |
Sweden
