| 2. Round | 13/08/2022 | Wolverhampton Wanderers | - | Fulham FC | 0:0 | ||||
| 3. Round | 20/08/2022 | Tottenham Hotspur | - | Wolverhampton Wanderers | 1:0 | ||||
| 4. Round | 28/08/2022 | Wolverhampton Wanderers | - | Newcastle United | 1:1 | ||||
| 5. Round | 31/08/2022 | AFC Bournemouth | - | Wolverhampton Wanderers | 0:0 | ||||
| 6. Round | 03/09/2022 | Wolverhampton Wanderers | - | Southampton FC | 1:0 |  |
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| 8. Round | 17/09/2022 | Wolverhampton Wanderers | - | Manchester City | 0:3 | ||||
| 9. Round | 01/10/2022 | West Ham United | - | Wolverhampton Wanderers | 2:0 | ||||
| 10. Round | 08/10/2022 | Chelsea FC | - | Wolverhampton Wanderers | 3:0 | ||||
| 12. Round | 18/10/2022 | Crystal Palace | - | Wolverhampton Wanderers | 2:1 | ||||
| 14. Round | 29/10/2022 | Brentford FC | - | Wolverhampton Wanderers | 1:1 | ||||
| 15. Round | 05/11/2022 | Wolverhampton Wanderers | - | Brighton & Hove Albion | 2:3 |  |
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| 16. Round | 12/11/2022 | Wolverhampton Wanderers | - | Arsenal FC | 0:2 | ||||
| 17. Round | 26/12/2022 | Everton FC | - | Wolverhampton Wanderers | 1:2 |
Portugal
