| 3. Round | 05/01/2022 | FC Cartagena | - | Valencia CF | 1:2 | ||||
| Round of 16 | 16/01/2022 | Atlético Baleares | - | Valencia CF | 0:1 | ||||
| Quarter-finals | 02/02/2022 | Valencia CF | - | Cádiz CF | 2:1 |  |
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| Semi-finals | 10/02/2022 | Athletic Club | - | Valencia CF | 1:1 | ||||
| Semi-finals | 02/03/2022 | Valencia CF | - | Athletic Club | 1:0 | |
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| Final | 23/04/2022 | Real Betis | - | Valencia CF | 5:4 pso |
Portugal
