| 1. Round | 11/08/2024 | Sheffield Wednesday | - | Plymouth Argyle | 4:0 |  |
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| 2. Round | 17/08/2024 | Plymouth Argyle | - | Hull City | 1:1 |  |
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| 3. Round | 24/08/2024 | Queens Park Rangers | - | Plymouth Argyle | 1:1 | ||||
| 4. Round | 31/08/2024 | Plymouth Argyle | - | Stoke City | 0:1 | ||||
| 5. Round | 14/09/2024 | Plymouth Argyle | - | Sunderland AFC | 3:2 | ||||
| 6. Round | 21/09/2024 | West Bromwich Albion | - | Plymouth Argyle | 1:0 | ||||
| 7. Round | 27/09/2024 | Plymouth Argyle | - | Luton Town | 3:1 | |
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| 8. Round | 01/10/2024 | Burnley FC | - | Plymouth Argyle | 1:0 | ||||
| 9. Round | 05/10/2024 | Plymouth Argyle | - | Blackburn Rovers | 2:1 | ||||
| 10. Round | 19/10/2024 | Cardiff City | - | Plymouth Argyle | 5:0 |  |
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| 25. Round | 01/01/2025 | Plymouth Argyle | - | Bristol City | 2:2 | ||||
| 19. Round | 14/01/2025 | Plymouth Argyle | - | Oxford United | 1:1 | ||||
| 27. Round | 18/01/2025 | Plymouth Argyle | - | Queens Park Rangers | 0:1 |
Netherlands
Guinea