| 5. Round | 08/09/2012 | Torquay United | - | Plymouth Argyle | 0:0 | ||||
| 11. Round | 06/10/2012 | Plymouth Argyle | - | AFC Wimbledon | 1:2 | ||||
| 12. Round | 13/10/2012 | Barnet FC | - | Plymouth Argyle | 1:4 | ||||
| 13. Round | 20/10/2012 | Plymouth Argyle | - | Rochdale AFC | 3:1 | ||||
| 14. Round | 23/10/2012 | Cheltenham Town | - | Plymouth Argyle | 2:1 | ||||
| 16. Round | 07/11/2012 | Plymouth Argyle | - | Burton Albion | 1:2 | ||||
| 20. Round | 24/11/2012 | Plymouth Argyle | - | Chesterfield FC | 0:1 | ||||
| 21. Round | 08/12/2012 | Plymouth Argyle | - | York City | 2:0 | ||||
| 22. Round | 15/12/2012 | Exeter City | - | Plymouth Argyle | 1:1 |  |
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| 23. Round | 22/12/2012 | Accrington Stanley | - | Plymouth Argyle | 1:1 | ||||
| 26. Round | 01/01/2013 | Bristol Rovers | - | Plymouth Argyle | 2:1 |
England