| 4. Round | 11/09/2010 | Hibernian FC | - | Inverness CT | 1:1 | ||||
| 5. Round | 18/09/2010 | Hibernian FC | - | Hamilton Academical | 1:1 | ||||
| 6. Round | 25/09/2010 | Celtic FC | - | Hibernian FC | 2:1 | ||||
| 7. Round | 02/10/2010 | St. Johnstone FC | - | Hibernian FC | 2:0 | ||||
| 10. Round | 30/10/2010 | Dundee United | - | Hibernian FC | 1:0 | ||||
| 11. Round | 07/11/2010 | Hibernian FC | - | Heart of Midlothian | 0:2 | ||||
| 12. Round | 10/11/2010 | Rangers FC | - | Hibernian FC | 0:3 | ||||
| 13. Round | 13/11/2010 | Hibernian FC | - | Motherwell FC | 2:1 | ||||
| 14. Round | 20/11/2010 | Inverness CT | - | Hibernian FC | 4:2 | ||||
| 15. Round | 27/11/2010 | Hibernian FC | - | St. Johnstone FC | 0:0 | ||||
| 18. Round | 18/12/2010 | Kilmarnock FC | - | Hibernian FC | 2:1 |  |
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| 19. Round | 26/12/2010 | Hibernian FC | - | Aberdeen FC | 1:2 | ||||
| 21. Round | 01/01/2011 | Heart of Midlothian | - | Hibernian FC | 1:0 |
England