| 4. Round | 22/09/2005 | Real Madrid | - | Athletic Club | 3:1 |  |
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| 6. Round | 02/10/2005 | Real Madrid | - | RCD Mallorca | 4:0 | ||||
| 11. Round | 26/10/2005 | Deportivo La Coruña | - | Real Madrid | 3:1 | ||||
| 9. Round | 29/10/2005 | Real Betis | - | Real Madrid | 0:2 |  |
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| 10. Round | 06/11/2005 | Real Madrid | - | Real Zaragoza | 1:0 | ||||
| 18. Round | 08/01/2006 | Villarreal CF | - | Real Madrid | 0:0 | |
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| 21. Round | 29/01/2006 | RC Celta | - | Real Madrid | 1:2 | ||||
| 22. Round | 04/02/2006 | Real Madrid | - | Espanyol Barcelona | 4:0 | ||||
| 23. Round | 11/02/2006 | Athletic Club | - | Real Madrid | 0:2 | |
England