| 1. Round | 04/10/2020 | Real Madrid [Women] | - | FC Barcelona [Women] | 0:4 | ||||
| 2. Round | 11/10/2020 | FC Barcelona [Women] | - | EDF Logroño [Women] | 6:0 |  |
|||
| 26. Round | 17/04/2021 | FC Barcelona [Women] | - | Deportivo La Coruña [Women] | 9:0 | ||||
| 16. Round | 20/04/2021 | FC Barcelona [Women] | - | UDG Tenerife Sur [Women] | 6:1 | ||||
| 15. Round | 28/04/2021 | Madrid CFF [Women] | - | FC Barcelona [Women] | 0:2 | ||||
| 29. Round | 09/05/2021 | UDG Tenerife Sur [Women] | - | FC Barcelona [Women] | 0:1 | ||||
| 28. Round | 19/05/2021 | FC Barcelona [Women] | - | Athletic Club [Women] | 8:0 | ||||
| 27. Round | 01/06/2021 | Atlético Madrid [Women] | - | FC Barcelona [Women] | 4:3 | ||||
| 32. Round | 06/06/2021 | FC Barcelona [Women] | - | Madrid CFF [Women] | 3:2 | |
|||
| 33. Round | 20/06/2021 | Real Sociedad [Women] | - | FC Barcelona [Women] | 1:4 | ||||
| 30. Round | 24/06/2021 | FC Barcelona [Women] | - | Sporting de Huelva [Women] | 5:0 | ||||
| 34. Round | 27/06/2021 | FC Barcelona [Women] | - | SD Eibar [Women] | 9:1 |  |
Spain