| 3. Round | 25/09/2022 | Villarreal CF [Women] | - | FC Barcelona [Women] | 1:4 | ||||
| 4. Round | 01/10/2022 | FC Barcelona [Women] | - | Madrid CFF [Women] | 7:0 |  |
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| 9. Round | 20/11/2022 | FC Barcelona [Women] | - | CD Alavés [Women] | 8:0 | ||||
| 10. Round | 27/11/2022 | Atlético Madrid [Women] | - | FC Barcelona [Women] | 1:6 | ||||
| 11. Round | 03/12/2022 | FC Barcelona [Women] | - | Real Sociedad [Women] | 2:1 | ||||
| 12. Round | 10/12/2022 | FC Barcelona [Women] | - | Alhama CF [Women] | 4:0 | ||||
| 16. Round | 25/01/2023 | FC Barcelona [Women] | - | Levante Las Planas [Women] | 7:0 | ||||
| 17. Round | 29/01/2023 | UDG Tenerife Sur [Women] | - | FC Barcelona [Women] | 0:6 | ||||
| 18. Round | 05/02/2023 | FC Barcelona [Women] | - | Real Betis [Women] | 7:0 | |
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| 22. Round | 17/03/2023 | FC Barcelona [Women] | - | Valencia CF [Women] | 5:1 | ||||
| 24. Round | 02/04/2023 | Alhama CF [Women] | - | FC Barcelona [Women] | 0:2 | ||||
| 27. Round | 30/04/2023 | FC Barcelona [Women] | - | Sporting de Huelva [Women] | 3:0 |  |
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| 29. Round | 13/05/2023 | FC Barcelona [Women] | - | Athletic Club [Women] | 3:0 |
Spain