| 24. Round | 10/02/2022 | Liverpool FC | - | Leicester City | 2:0 | ||||
| 26. Round | 19/02/2022 | Liverpool FC | - | Norwich City | 3:1 |  |
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| 19. Round | 23/02/2022 | Liverpool FC | - | Leeds United | 6:0 | ||||
| 28. Round | 05/03/2022 | Liverpool FC | - | West Ham United | 1:0 | ||||
| 29. Round | 12/03/2022 | Brighton & Hove Albion | - | Liverpool FC | 0:2 | |
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| 27. Round | 16/03/2022 | Arsenal FC | - | Liverpool FC | 0:2 | ||||
| 32. Round | 10/04/2022 | Manchester City | - | Liverpool FC | 2:2 | ||||
| 30. Round | 19/04/2022 | Liverpool FC | - | Manchester United | 4:0 | |
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| 34. Round | 24/04/2022 | Liverpool FC | - | Everton FC | 2:0 | ||||
| 35. Round | 30/04/2022 | Newcastle United | - | Liverpool FC | 0:1 | ||||
| 36. Round | 07/05/2022 | Liverpool FC | - | Tottenham Hotspur | 1:1 | |
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| 33. Round | 10/05/2022 | Aston Villa | - | Liverpool FC | 1:2 | ||||
| 38. Round | 22/05/2022 | Liverpool FC | - | Wolverhampton Wanderers | 3:1 |
Colombia
