| 1. Round | 06/08/2022 | Fulham FC | - | Liverpool FC | 2:2 | ||||
| 2. Round | 15/08/2022 | Liverpool FC | - | Crystal Palace | 1:1 |  |
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| 3. Round | 22/08/2022 | Manchester United | - | Liverpool FC | 2:1 | ||||
| 4. Round | 27/08/2022 | Liverpool FC | - | AFC Bournemouth | 9:0 | |
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| 5. Round | 31/08/2022 | Liverpool FC | - | Newcastle United | 2:1 | ||||
| 6. Round | 03/09/2022 | Everton FC | - | Liverpool FC | 0:0 | ||||
| 9. Round | 01/10/2022 | Liverpool FC | - | Brighton & Hove Albion | 3:3 | ||||
| 10. Round | 09/10/2022 | Arsenal FC | - | Liverpool FC | 3:2 | |
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| 31. Round | 17/04/2023 | Leeds United | - | Liverpool FC | 1:6 | ||||
| 32. Round | 22/04/2023 | Liverpool FC | - | Nottingham Forest | 3:2 | ||||
| 33. Round | 26/04/2023 | West Ham United | - | Liverpool FC | 1:2 | ||||
| 34. Round | 30/04/2023 | Liverpool FC | - | Tottenham Hotspur | 4:3 | |
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| 28. Round | 03/05/2023 | Liverpool FC | - | Fulham FC | 1:0 | ||||
| 35. Round | 06/05/2023 | Liverpool FC | - | Brentford FC | 1:0 | ||||
| 36. Round | 15/05/2023 | Leicester City | - | Liverpool FC | 0:3 | ||||
| 37. Round | 20/05/2023 | Liverpool FC | - | Aston Villa | 1:1 | ||||
| 38. Round | 28/05/2023 | Southampton FC | - | Liverpool FC | 4:4 |
Colombia
