| 1. Round | 11/08/2007 | Hull City | - | Plymouth Argyle | 2:3 | ||||
| 3. Round | 25/08/2007 | Barnsley FC | - | Plymouth Argyle | 3:2 |  |
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| 5. Round | 15/09/2007 | Plymouth Argyle | - | Cardiff City | 2:2 | ||||
| 7. Round | 22/09/2007 | Stoke City | - | Plymouth Argyle | 3:2 | ||||
| 8. Round | 29/09/2007 | Plymouth Argyle | - | Wolverhampton Wanderers | 1:1 | |
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| 9. Round | 02/10/2007 | Plymouth Argyle | - | Crystal Palace | 1:0 | ||||
| 10. Round | 06/10/2007 | Blackpool FC | - | Plymouth Argyle | 0:0 | ||||
| 12. Round | 23/10/2007 | Charlton Athletic | - | Plymouth Argyle | 1:2 | ||||
| 21. Round | 08/12/2007 | Plymouth Argyle | - | Bristol City | 1:1 |
England