| 5. Round | 25/09/2010 | Athletic Club | - | FC Barcelona | 1:3 | ||||
| 6. Round | 03/10/2010 | FC Barcelona | - | RCD Mallorca | 1:1 | ||||
| 8. Round | 23/10/2010 | Real Zaragoza | - | FC Barcelona | 0:2 | ||||
| 12. Round | 20/11/2010 | UD Almería | - | FC Barcelona | 0:8 |  |
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| 17. Round | 02/01/2011 | FC Barcelona | - | Levante UD | 2:1 | ||||
| 18. Round | 08/01/2011 | Deportivo La Coruña | - | FC Barcelona | 0:4 | ||||
| 30. Round | 02/04/2011 | Villarreal CF | - | FC Barcelona | 0:1 | ||||
| 31. Round | 09/04/2011 | FC Barcelona | - | UD Almería | 3:1 |  |
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| 33. Round | 23/04/2011 | FC Barcelona | - | CA Osasuna | 2:0 | ||||
| 34. Round | 30/04/2011 | Real Sociedad | - | FC Barcelona | 2:1 | |
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| 37. Round | 15/05/2011 | FC Barcelona | - | Deportivo La Coruña | 0:0 | ||||
| 38. Round | 21/05/2011 | Málaga CF | - | FC Barcelona | 1:3 |
Italy
Brazil 
