| 2. Round | 23/08/2019 | Levante UD | - | Villarreal CF | 2:1 | ||||
| 9. Round | 20/10/2019 | Espanyol Barcelona | - | Villarreal CF | 0:1 | ||||
| 10. Round | 25/10/2019 | Villarreal CF | - | CD Alavés | 4:1 | ||||
| 19. Round | 05/01/2020 | Real Sociedad | - | Villarreal CF | 1:2 |  |
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| 20. Round | 19/01/2020 | Villarreal CF | - | Espanyol Barcelona | 1:2 | ||||
| 21. Round | 25/01/2020 | CD Alavés | - | Villarreal CF | 1:2 | ||||
| 25. Round | 23/02/2020 | Atlético Madrid | - | Villarreal CF | 3:1 | ||||
| 26. Round | 01/03/2020 | Athletic Club | - | Villarreal CF | 1:0 | ||||
| 27. Round | 08/03/2020 | Villarreal CF | - | CD Leganés | 1:2 | |
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| 28. Round | 13/06/2020 | RC Celta | - | Villarreal CF | 0:1 | ||||
| 29. Round | 16/06/2020 | Villarreal CF | - | RCD Mallorca | 1:0 | |
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| 30. Round | 19/06/2020 | Granada CF | - | Villarreal CF | 0:1 | |
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| 31. Round | 22/06/2020 | Villarreal CF | - | Sevilla FC | 2:2 | |
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| 33. Round | 01/07/2020 | Real Betis | - | Villarreal CF | 0:2 | |
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| 34. Round | 05/07/2020 | Villarreal CF | - | FC Barcelona | 1:4 | ||||
| 35. Round | 08/07/2020 | Getafe CF | - | Villarreal CF | 1:3 | ||||
| 36. Round | 13/07/2020 | Villarreal CF | - | Real Sociedad | 1:2 | ||||
| 38. Round | 19/07/2020 | Villarreal CF | - | SD Eibar | 4:0 |
Spain
