| Group D | 14/09/2005 | Villarreal CF | - | Manchester United | 0:0 | ||||
| Group D | 27/09/2005 | Lille OSC | - | Villarreal CF | 0:0 |  |
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| Group D | 18/10/2005 | Villarreal CF | - | SL Benfica | 1:1 | ||||
| Group D | 22/11/2005 | Manchester United | - | Villarreal CF | 0:0 | |
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| Round of 16 | 22/02/2006 | Rangers FC | - | Villarreal CF | 2:2 | ||||
| Round of 16 | 07/03/2006 | Villarreal CF | - | Rangers FC | 1:1 | |
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| Quarter-finals | 04/04/2006 | Villarreal CF | - | Inter | 1:0 | |
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| Semi-finals | 19/04/2006 | Arsenal FC | - | Villarreal CF | 1:0 | |
Italy