| Copa del Rey | 04/01/06 | Villarreal CF | - | Valencia CF | 0:2 | ||||
| Primera | 12/03/06 | RCD Mallorca | - | Villarreal CF | 1:1 |  |
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| Primera | 13/05/06 | Villarreal CF | - | Racing Santander | 2:0 | ||||
| Copa del Rey | 08/11/06 | Villarreal CF | - | CD Castellón | 2:0 | |
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| Primera | 10/12/06 | RC Celta | - | Villarreal CF | 1:1 | ||||
| Primera | 09/06/07 | Villarreal CF | - | Athletic Club | 3:1 | |
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