| 3. Round | 17/08/2013 | AS Livorno | - | AC Siena | 0:1 |  |
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| Round of 16 | 15/01/2014 | Calcio Catania | - | AC Siena | 1:4 |  |
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| Quarter-finals | 23/01/2014 | ACF Fiorentina | - | AC Siena | 2:1 |
| 3. Round | 17/08/2013 | AS Livorno | - | AC Siena | 0:1 | |
|||
| Round of 16 | 15/01/2014 | Calcio Catania | - | AC Siena | 1:4 | |
|||
| Quarter-finals | 23/01/2014 | ACF Fiorentina | - | AC Siena | 2:1 |
| Ângelo Mariano de Almeida | |
| Born: | 12.06.1981 |
| Place of birth: |
Salvador de Bahia, 
Brazil |
| Nationality: |
Brazil
|
| Height: | 175 cm |
| Weight: | 76 kg |
| Position(s): | Right Back Right Midfielder |
| Foot: | right |